Flexible high-loading particle-reinforced polyurethane magnetic nanocomposite fabrication through particle-surface-initiated polymerization

نویسندگان

  • Zhanhu Guo
  • Sung Park
  • Suying Wei
  • Tony Pereira
  • Monica Moldovan
  • Amar B Karki
  • David P Young
  • Thomas Hahn
چکیده

Flexible high-loading nanoparticle-reinforced polyurethane magnetic nanocomposites fabricated by the surface-initiated polymerization (SIP) method are reported. Extensive field emission scanning electron microscopic (SEM) and atomic force microscopic (AFM) observations revealed a uniform particle distribution within the polymer matrix. X-ray photoelectron spectrometry (XPS) and differential thermal analysis (DTA) revealed a strong chemical bonding between the nanoparticles and the polymer matrix. The elongation of the SIP nanocomposite under tensile test was about four times greater than that of the composite fabricated by a conventional direct mixing fabrication method. The nanocomposite shows particle-loading-dependent magnetic properties, with an increase of coercive force after the magnetic nanoparticles were embedded into the polymer matrix, arising from the increased interparticle distance and the introduced polymer–particle interactions. (Some figures in this article are in colour only in the electronic version)

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Nanocomposite Fabrication Through Particle Surface Initiated Polymerization

Magnetic nanoparticles (NPs) have attracted much interest due to their special physicochemical properties such as enhanced magnetic moment and coercivity different from the bulk and atomic counterparts. Incorporation of the inorganic NPs into a polymer matrix has extended the particle applications such as in high-sensitivity chemical gas sensors due to the advantages of polymeric nanocomposites...

متن کامل

Magnetic and electromagnetic evaluation of the iron nanoparticle filled polyurethane nanocomposites

The magnetic and electromagnetic wave absorption behavior of a flexible ironnanoparticle reinforced polyurethane nanocomposite is reported. Surface-initiatedpolymerization (SIP) method was utilized to fabricate high quality nanocomposites with uniform particle distribution and tunable particle loading (up to 65 wt.%). The enhancement of coercive force is observed when the nanoparticles are embe...

متن کامل

Synthesis of polymer/inorganic nanocomposite films using highly porous inorganic scaffolds.

Polymeric/inorganic nanocomposite films have been fabricated through a combination of flame-spray-pyrolysis (FSP) made inorganic scaffold and surface initiated polymerization of cyanoacrylate. The highly porous structure of pristine SnO(2) films allows the uptake of cyanoacrylate and the polymerization is surface initiated by the water adsorbed onto the SnO(2) surface. Scanning electron microsc...

متن کامل

Fabrication of black printing toner through in situ polymerization: An effective way to increase conversion

Styrene-acrylate copolymer was synthesized in presence of carbon black through heterogeneous polymerization. The percentage of monomer conversion was measured by gravimetric method, also PSA, SEM, DSC and GPC were used for studying the particle size and particle size distribution, morphology, thermal properties and molecular weight, respectively. As well as color properties were characterized b...

متن کامل

Improvement of Soft Tooling Process Through Particle Reinforcement with Polyurethane Mould

Use of conventional flexible polymeric mould materials yields to longer solidification time of (wax/plastic) patterns in soft tooling process, thereby reducing the rapidity of the process to a great extent, which is not desirable in present competitive market. In this work, approach of particle-reinforcement with mould materials is introduced to reduce the cycle time of Soft tooling process and...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2007